Information on this page: Mass spectrum (electron ionization) References; Notes; Other data available: Molybdenum hexacarbonyl and related derivatives can be used as a catalyst in organic synthesis, for example, for alkyne metathesis and Pauson -Khand reaction. In addition, molybdenum powder is used as a plant fertilizer. Bis(t-butylimido)bis(dimethylamino)molybdenum, Dicarbonyl(pentamethylcyclopentadienyl)molybdenum dimer, P260-P262-P280-P301 + P310 + P330-P302 + P352 + P310-P304 + P340 + P310-P403 + P233, METAL CARBONYLS, SOLID, N.O.S. Catalytic reactions of formate: Part 1. Formula: C6MoO6. Molybdenum hexacarbonyl was detected in trace concentrations in the gaseous exhalations of sewage sludge. Thin Solid Films 2000, 358, 90. Packaging 10, 50, 250 g in glass bottle Molybdenum hexacarbonyl weighs 1.96 gram per cubic centimeter or 1 960 kilogram per cubic meter, i.e. Molybdenum hexacarbonyl and related derivatives can be used as a catalyst in organic synthesis, for example, for alkyne metathesis and Pauson -Khand reaction. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. Information on this page: Notes; Other data available: Gas phase thermochemistry data School of Chemistry @ Pietermaritzburg University of KwaZulu Natal Chemistry 310 Substitution reaction of Molybdenum Hexacarbonyl: the use of infrared spectroscopy as a structural tool in metal carbonyl chemistry. Find where to buy products from suppliers in the USA, including: distributors, industrial manufacturers in America, bulk supplies and wholesalers of raw ingredients & finished goods.. Search for products or services, then visit the American suppliers website for prices, SDS or more information. Molybdenum is an essential mineral in the body, just like iron and magnesium. Have a unique need? Use the product Attributes below to configure the comparison table. Move out of the dangerous area. If not breathing, give artificial respiration. [3] Mo(CO) 6 is also a popular reagent in organometallic synthesis [4] because one or more CO ligands can be displaced by other donor ligands. They can be represented in the presence of Devarda alloy as halide acceptor by reductive Hochdruckcarbonylierung of molybdenum ( V) chloride. Molybdenum hexacarbonyl. Molybdenum hexacarbonyl MSDS# 04603 Section 1 - Chemical Product and Company Identification MSDS Name: Molybdenum hexacarbonyl Catalog Numbers: AC190390000, AC190390100, AC190390250, AC190390500, AC190392500 Synonyms: Hexacarbonylmolybdenum. NSC 173702. The development of a method that uses molybdenum hexacarbonyl [Mo (CO) 6] as carbon monoxide (CO) surrogate for the palladium‐catalyzed reductive cyclization of nitroalkenes into indoles or thienopyrroles is reported. The dipole moment of the complex is 0 Debye. NSC215198. The resulting air-sensitive compound is used as a source of Mo ( CO) 3 fragment. SpectraBase Compound ID: CNV2yZUx6rM: InChI: InChI=1S/6CO.Mo/c6*1-2; InChIKey: KMKBZNSIJQWHJA-UHFFFAOYSA-N Google Search Mol Weight: 264.01 g/mol: Molecular Formula: C6MoO6: Exact Mass: 265.874893 g/mol: Dangerous Substances Directive (67/548/EEC). Rinse mouth with water. Ereztech manufactures and sells this product in small and bulk volumes. Molybdenum hexacarbonyl (Mo(CO) 6) is the starting product for the manufacture of organomolybdenum dyes. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. We're here to answer any questions you have. Molybdenum hexacarbonyl is represented by the reduction of Molybdänhexachlorid ( MoCl6 ) under Kohlenstoffmonoxiddruck. To purchase Molybdenum hexacarbonyl contact us at sales@ereztech.com, FAQs on Custom Metal-Organic Precursors Used for ALD, Careers at Ereztech: Leader in Metal-Organics, Auditing Custom Metal-Organics Manufacturing & Production, Innovative Approach to Scaling Up Silicon Tetraiodide, Scaling Up Cobalt Octacarbonyl and Its Derivatives, Ereztech manufactures and sells this product in small and bulk volumes. 2015, 68, 60-66. Many metal carbonyls are similar photochemically activated. It is sparingly soluble in nonpolar organic solvents. It is a stable 18- Valenzelektronenkomplex. Molybdenum hexacarbonyl is widely used in electron beam-induced deposition technique - it is easily vaporized and decomposed by the electron beam providing a convenient source of molybdenum atoms. Consult a physician. Abstract. [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]. These compounds are difficult to prepare and may decompose on exposure to air. Product # Description 199958: Molybdenumhexacarbonyl, 98%, 577766: Molybdenumhexacarbonyl, ≥99.9% trace metals … This product also utilized as a precursor for the manufacture of organomolybdenum dyes and for Molybdenum plating by thermal decomposition. Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions. NSC173702. NSC-215198. However, it is often made ​​in this manner in the laboratory, because the required equipment is expensive, and the compound can be acquired inexpensively. The oxidation state 0 is possible with carbon monoxide as ligand, such as in molybdenum hexacarbonyl, Mo(CO) 6. Foods. A. UV photolysis of molybdenum hexacarbonyl in tetrahydrofuran provides a substituted THF complex of Mo ( CO) 5 (THF). Opt. Hamelmann, F. et al. Use this link for bookmarking this species for future reference. Molybänhexacarbonyl reacts with 2,2 '-bipyridine in a heteroleptic complex of Mo ( CO) 4 ( bipy). DTXSID70894074. [5] Consult a physician. It is increasingly used for molybdenum plating by thermal decomposition. CHEBI:30508. The chart below shows the calculated isotope pattern for the formula Mo(CO) 6 with the most intense ion set to 100%. References. TSCA: TSCA. EINECS 237-713-3. We've been creating custom solutions since 1991. Never give anything by mouth to an unconscious person. Wash off with soap and plenty of water. If breathed in, move person into the fresh air. Dicyclopentadiene has an irritating odour and should be considered as toxic. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. Do NOT induce vomiting. In organic synthesis, its derivatives are employed as catalysts. For additional analytical information or details about purchasing Molybdenum hexacarbonyl contact us at sales@ereztech.com, If you don’t see the needed lot of Molybdenum hexacarbonyl below please contact customer support at sales@ereztech.com, Lot# 5/R/1/0618 Lot# 5/R/1/Mo50/419 Lot# 5R01620 Lot# 5R1920. Molybdenum hexacarbonyl is used in the technique of electron beam -induced deposition of a precursor. Consult a physician. The table shows element percentages for Mo(CO) 6 (molybdenum hexacarbonyl). Like all metal carbonyls is molybdenum hexacarbonyl from improper handling of a source of volatile metal and carbon monoxide. Today 2003, 87 (1-4), 107-115. Used in the grafting of silica, as a catalyst for epoxidation of olefins, in the adsorption of organosulfur compounds from liquid fuels, as a precursor for the manufacture of organomolybdenum dyes and for Molybdenum plating by thermal decomposition. They have specialised small volume uses as for example catalysts in fine chemicals synthesis. Investigation of optical nonlinearity of C60 doped acetylenedicarboxylic acid polymer. The two piperidine ligands in this yellow compound are labile bound, so that other ligands can be introduced under mild conditions. Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene. Molybdenum hexacarbonyl is used in the technique of electron beam -induced deposition of a precursor. Use this link for bookmarking this species for future reference. Glass ampules, bottles or metal ampules or bubblers are available for packaging. (Hexacarbonylmolybdenum). A well known example is molybdenum hexacarbonyl, Mo(CO) 6. Application: Forms X-ray mirrors by alternating deposition with SiO2 by PECVD.1. ). Molybdenum hexacarbonyl, due to its ability easily vaporized and decomposed by the electron beam, is widely used in electron beam-induced deposition technique. Molybdenum-based technical chemicals exploit the versatility of molybdenum chemistry in oxidation states. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. It is used as a reagent in organometallic synthesis because of the displacement of carbonyl ligands by other donor ligands. Molybdenum and Tungsten Imido Alkylidene N-Heterocyclic Carbene Catalysts Bearing Cationic Ligands for Use in Biphasic Olefin Metathesis. The six Kohlenstoffmonoxidliganden are positioned radially around the central molybdenum atom. [7] Safety and handling. Substance name : MOLYBDENUM HEXACARBONYL Product code : INMO030 Formula : C6MoO6 Synonyms : MOLYBDENUM CARBONYL; HEXACARBONYLMOLYBDENUM Chemical family : METAL COMPOUND 1.2. We can help. Hexacarbonyl Suppliers USA. Reference: 1. Good yields of the corresponding products have been obtained with wide functional group tolerance and excellent regioselectivity. Use this link for bookmarking this species for future reference. The compound is relatively stable in air. Laser Technol. It behaves similarly to the analogous tungsten complex. (Select up to %1% total) Brand Reaction Suitability Assay. DOI: 10.1016/0304-5102(93)85074-4. Molybdenum hexacarbonyl (also called molybdenum carbonyl) is the chemical compound with the formula Mo(CO) 6.This colorless solid, like its chromium and tungsten analogues, is noteworthy as a volatile, air-stable derivative of a metal in its zero oxidation state. The thermal reaction of molybdenum hexacarbonyl with piperidine provides a complex in which two Kohlenstoffmonoxidliganden piperidine are replaced by Mo (CO ) 4 ( piperidine ) 2 You can also view suppliers in Australia, NZ or the UK. Catal. Show this safety data sheet to the doctor in attendance. | All rights reserved. Molybdenum hexacarbonyl, due to its ability easily vaporized and decomposed by the electron beam, is widely used in electron beam-induced deposition technique. Read "ChemInform Abstract: Molybdenum Hexacarbonyl as Catalyst for the Dehydrochlorination of Trichloromethyl Group Containing Compounds., ChemInform" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Ereztech synthesizes and sells additional MO-compounds. ©2021 Ereztech LLC. Molybdenum hexacarbonyl is a chemical compound having the formula Mo (CO) 6 For additional analytical information or details about purchasing Molybdenum hexacarbonyl contact us at, If you don’t see the needed lot of Molybdenum hexacarbonyl below please contact customer support at, Ereztech synthesizes and sells additional, To purchase Molybdenum hexacarbonyl contact us at. Molybdenum carbonyl (Mo(CO)6) (8CI) Like all metal carbonyls, Mo(CO) 6 is … For example, the reaction of [Mo (CO ) 4 ( piperidine ) 2] and triphenyl phosphine in dichloromethane, the cis-substituted [Mo ( CO) 4 (PPh3) 2 ] complex. NSC-173702. Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-Molybdenum carbonyl (Mo(CO)6) Molybdenum carbonyl (Mo2(CO)12) hexacarbonylmolybdenum(0) Mo (C O)6. The reaction with allyl chloride gives [ MoCl (allyl ) (CO ) 2 ( MeCN) 2]. By refluxing in acetonitrile molybdenum hexacarbonyl is converted to the tris -acetonitrile derivative. Details of the supplier of the safety data sheet Emergency Telephone Number Subscribe to our news feed for new products, industry news and trends. The Kohlenstoffmonoxidliganden in molybdenum hexacarbonyl can be substituted by other ligands. The Mo-C distance is 206 pm. Forms used for industrial purposes include molybdenum oxide, molybdenum trioxide, molybdenum hexacarbonyl and molybdenum sulfide. Molybdenum hexacarbonyl has an octahedral ( Oh). Consult a physician. density of molybdenum hexacarbonyl is equal to 1 960 kg/m³; at 20°C (68°F or 293.15K) at standard atmospheric pressure.In Imperial or US customary measurement system, the density is equal to 122.359 pound per cubic foot [lb/ft³], or 1.133 ounce per cubic inch [oz/inch³] . This colorless compound, like its chromium and molybdenum analogs, is noteworthy as a volatile, air-stable derivative of tungsten in its zero oxidation state. Journal of Molecular Catalysis 1993, 80 (2) , 151-163. Industrially, molybdenum compounds (about 14% of world production of the element) are used in high-pressure and high-temperature applications as pigments and catalysts. Molybdenum hexacarbonyl is very toxic and relatively volatile: wear gloves and weigh it out in the hood. Knowledgeable staff are standing by. It is used as a reagent in organometallic synthesis because of the displacement of carbonyl ligands by other donor ligands. Uses advised against Food, drug, pesticide or biocidal product use. [Mo]. Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Molybdenum hexacarbonyl is widely used in electron beam-induced deposition technique - it is easily vaporized and decomposed by the electron beam providing a convenient source of molybdenum atoms. Zidan, M. D.; Allaf, A. W.; Allahham, A.; Zier, A. : AC190390000; AC190390100; AC190390500; AC190392500 CAS-No 13939-06-5 Synonyms Hexacarbonylmolybdenum Recommended Use Laboratory chemicals. MOLYBDENUM CARBONYL View entire compound with free spectra: 3 FTIR, and 4 Raman. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Chemical intermediate For research and industrial use only 1.3. As it evaporates easily and decays by the electron beam, it provides an easily accessible source of molybdenum atoms. Template: Infobox chemical / molecular formula search is not possible. Kadono, T.; Kubota, T.; Okamoto, Y. Hydrodesulfurization over intrazeolite molybdenum nitride clusters prepared by using hexacarbonyl molybdenum as a precursor. The reaction is carried out in a 250 mL round bottom flask fitted with an ordinary Liebig condenser (NB Don't use a double-surface condenser or a spiral condenser! Photocatalytic hydrogen production from formate with chromium hexacarbonyl. Company Identification: Acros Organics BVBA Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium With molybdenum hexacarbonyl as the carbon monoxide source, a general palladium‐catalyzed carbonylative transformation of the C−H bond on aromatic rings to produce esters has been developed. Molybdenum disulphide (MoS 2) is employed as a heat-resistant lubricant or a lubricant additive. Information on this page: Reaction thermochemistry data; Mass spectrum (electron ionization) References; Notes Molybdenum hexacarbonyl CAS 13939-06-5 WIKI information includes physical and chemical properties, USES, security data, NMR spectroscopy, computational chemical data and more. Product Name Molybdenum hexacarbonyl Cat No. This colorless compound is chromium and tungsten as its analogs, a volatile, relatively air- stable complex of molybdenum in the oxidation state zero. Use this link for bookmarking this species for future reference. The wavenumber of the CO stretching vibration of the free νCO carbon monoxide is at 2004 cm -1. Show More. Element % C: 27.30: Mo: 36.34: O: 36.36: Isotope pattern for Mo(CO) 6. Molybdenum carbonyl. Ljudmila Bronshtein, Helge Lemmetyinen, Elena Mirzoeva, Pjotr Valetsky. Glass ampules, bottles or, are available for packaging. Examples of octahedral compounds are sulfur hexafluoride SF 6 and molybdenum hexacarbonyl Mo(CO) 6. Molybdenum hexacarbonyl agent detailed information in Haz-Map database. | All trademarks are property of their respective owners. Foods high in molybdenum include legumes, nuts, dairy products, cereal grains and leafy green vegetables. Synonym: Hexacarbonylmolybdenum, Molybdenumhexacarbonyl, Molybdenum carbonyl, CAS Number 13939-06-5 | MDL Number MFCD00003466 | EC Number 237-713-3. Vibration of the complex is 0 Debye and bulk volumes ; Hexacarbonylmolybdenum Chemical family metal... Zier, a 0 Debye include legumes, nuts, dairy products, industry news and trends glass,! Be considered as toxic improper handling of a source of molybdenum atoms air-sensitive is! -Induced deposition of a precursor: 4: no reaction with allyl gives! The UK uses advised against Food, drug, pesticide or biocidal product use drug pesticide... Under neutral conditions % total ) Brand reaction Suitability Assay or metal ampules or bubblers available. 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Future reference are employed as a precursor converted to the tris -acetonitrile derivative be substituted by other donor.... Weigh it out in the presence of Devarda alloy as Halide acceptor by Hochdruckcarbonylierung! Be considered as toxic by PECVD.1 Food, drug, pesticide or biocidal product use technical chemicals the... Carbon monoxide is at 2004 cm -1 zidan, M. D. ; Allaf, A. ;,! Mfcd00003466 | EC Number 237-713-3 neutral conditions in electron beam-induced deposition technique carbon monoxide is at cm! Also view suppliers in Australia, NZ or the UK for future reference Allaf, ;. Is an essential mineral in the gaseous exhalations of sewage sludge addition, hexacarbonyl..., NZ or the UK future reference six Kohlenstoffmonoxidliganden are positioned radially around the central molybdenum atom precursor for manufacture! Substance name: molybdenum carbonyl view entire compound with free spectra: 3 FTIR, and 4.! Sells this product also utilized as a reagent in organometallic synthesis because of the products... Uv photolysis of molybdenum hexacarbonyl ) as catalysts code: INMO030 Formula: C6MoO6:. Increasingly used for molybdenum plating by thermal decomposition molybdenum-based technical chemicals exploit versatility. Hexacarbonyl was detected in trace concentrations in the presence of Devarda alloy as Halide acceptor by reductive Hochdruckcarbonylierung of chemistry. -Acetonitrile derivative person into the fresh air in tetrahydrofuran provides a substituted THF of!, dairy products, cereal grains and leafy green vegetables species for future reference known example is hexacarbonyl., 151-163 leafy green vegetables Formula: C6MoO6 Synonyms: molybdenum hexacarbonyl due... Beam-Induced deposition technique Bearing Cationic ligands for use in Biphasic Olefin Metathesis provides substituted! Shows element percentages for Mo ( CO ) 6 free νCO carbon monoxide as ligand, as! Manufacture of organomolybdenum dyes and for molybdenum plating by thermal decomposition reduction of Molybdänhexachlorid MoCl6! Number 13939-06-5 | MDL Number MFCD00003466 | EC Number 237-713-3 to answer any questions you have / Formula! Are available for packaging, nuts, dairy products, cereal grains leafy! View suppliers in Australia, NZ or the UK of water for at least 15 minutes consult. 2 ( MeCN ) 2 ( MeCN ) 2 ( MeCN ) 2 ( MeCN 2. Thf complex of Mo ( CO ) 6 carbonyl ligands by other ligands minutes and consult a.. The product Attributes below to configure the comparison table such as in molybdenum include legumes, nuts, dairy,! Be represented in the technique of electron beam, is widely used in electron beam-induced technique! The displacement of carbonyl ligands by other donor ligands use in Biphasic Olefin Metathesis for Z-Selective Cross-Metathesis Cyclooctene! The wavenumber of the complex is 0 Debye EC Number 237-713-3 reaction Suitability Assay C6MoO6 Synonyms: molybdenum carbonyl entire... Provides a substituted THF complex of Mo ( CO ) 5 ( )! Are property of their respective owners Pjotr Valetsky of volatile metal and carbon monoxide -induced deposition a. With wide functional group tolerance and excellent regioselectivity body, just like iron and magnesium of the products... Of the free νCO carbon monoxide is at 2004 cm -1 or bubblers are for...: Infobox Chemical / Molecular Formula search is not possible the hood, drug, pesticide or product... Molybdänhexachlorid ( MoCl6 ) under Kohlenstoffmonoxiddruck it is used as a source of chemistry. Complex of Mo ( CO ) 2 ( MeCN ) 2 ( MeCN ) 2 ( MeCN ) (... Use this link for bookmarking this species for future reference hexacarbonyl, Mo ( CO ).. By the electron beam -induced deposition of a precursor or the UK fresh air:... Ampules, bottles or metal ampules or bubblers are available for packaging the Kohlenstoffmonoxidliganden in hexacarbonyl! And trends other ligands vaporized and decomposed by the electron beam -induced of... Lubricant additive metal ampules or bubblers are available for packaging industrial purposes include molybdenum oxide, molybdenum powder used. The comparison table is very toxic and relatively volatile: wear gloves weigh...